姓名：徐大乾

职称职务：副教授/化工系主任

学科专业：化工专业

Email：daqianxu@126.com

【个人简历】

徐大乾，理学博士，兰州城市学院欧洲杯买球赛的app化工系主任、甘肃省化学会化工专业委员会委员，硕士毕业于中科院兰州化学物理研究所化学工程专业，博士毕业于西北师范大学有机化学专业。先后在蓝星清洗股份有限公司、中科院兰州化学物理研究所从事工程、科研等工作，2018.7至今兰州城市学院化工系从事教学科研工作。目前承担国家自然科学基金地区基金一项，在Chem.Commun.,Green Chemistry, ACS Catal., Org. Lett., Dalton, Org. Bio. Chem.等杂志上发表论文20余篇,指导学生获得甘肃省第一届化工设计大赛二等奖、第七届中国国际互联网+大学生创新创业大赛甘肃省分赛高教主赛道铜奖，获得校级优秀实习指导教师、优秀毕业论文指导教师、优秀实习组织者等。

【教学】

化工设备机械基础、化工制图、文献检索

【研究领域】

主要从事催化设计合成及应用研究

【研究项目】

国家自然科学基金委员会，地区基金，22062010，天然氨基酸衍生苯并咪唑骨架类配体设计合成及应用研究， 2021.01-2024.12，40万

【代表性论文】

（1）Daqian Xu, Qiangsheng Sun, Jin Lin, Wei Sun, Ligand regulation for ma- nganese-catalyzed enantioselective epoxidation of olefins without acid. Chem. Commun., 2020, 56, 13101-13104.

（2）Daqian Xu, Wenfang Wang, Chengxia, Miao, Qiaohong, Zhang, Chungu Xia, Wei Sun, Green Chem., 2013, 15, 2975-2980.

（3）Bin Qiu, Daqian Xu, Qiangsheng Sun, Chengxia Miao, Yong-Min Lee, Xiao-Xi Li, Wonwoo Nam, Wei Sun. Highly Enantioselective Oxidation of Spirocyclic Hydrocarbons by Bioinspired Manganese Catalysts and Hydrogen Peroxide ACS Catalysis, 2018, 8, 2479–2487.

（4）Bin Qiu, Daqian Xu, Qiangsheng Sun, Jin Lin, Wei Sun*, Manganese-Catalyzed Asymmetric Oxidation of Methylene C-H of Spirocyclic Oxindoles and Dihydroquinolinones with Hydrogen Peroxide, Org. Lett., 2018, http://dx.doi.org/10.1021/acs.orglett.8b03652

（5）Daqian Xu, Qiangsheng Sun, Zhengjun Quan, Wei Sun, Xicun Wang. Cobalt-catalyzed Dimerization and Homocoupling of Terminal Alkynes. Asian J. Org. Chem., 2018, 7, 155–159.

（6） Daqian Xu, Shoufeng Wang, Zhiqiang Shen, Chungu Xia, Wei Sun,. Org. Biomio. Chem., 2012, 10, 2730–2732.

（7） Daqian Xu, Qiangsheng Sun, Zhengjun Quan, Wei Sun, Xicun Wang. The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction. Tetrahedron:Asymmetry, 2017, 28, 954–963.

（8）Wenfang Wang, Daqian Xu, Qiangsheng Sun, Wei Sun. Chemistry - An Asian Journal., DOI: 10.1002/asia.201800068.

（9） Junyi Du, Daqian Xu, Chunxi Zhang, Chungu Xia, Yong Wang, Wei Sun. Synthesis, characterization, and reactivity of a side-on manganese(III ) –peroxo complex bearing a pentadentate aminopyridine ligand. Dalton Trans., 2016, 45, 10131 –10135.

（10）Xianghua Zeng, Daqian Xu, Chengxia Miao, Chungu Xia, Wei Sun. Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C–C double bonds and recombination of aromatic groups. RSC Adv., 2014, 4, 46494 –46497.

（11）Xiaoe Wang, Daqian Xu, Chengxia Miao, Qiaohong Zhang, Wei Sun. N-Bromosuccinimide as an oxidant for the transition-metal-free synthesis of 2-aminobenzoxazoles from benzoxazoles and secondary amines. Org. Biomol. Chem., 2014, 12, 3108 –3113.